Issue 32, 2011

Approaching polymetallic ‘Assemblies of Assemblies’ using ligands with multiple functionality – novel Mn10M2 (M = alkali metal) chains with ‘ionophoric’ end cavities

Abstract

A tri-functional ligand with hydrazone, oxime and o-vanillin subunits uses separate encoded coordination instructions to create a novel extended spin-coupled cluster where the hydazone oxygen and oxime groups of three ligands combine to create bridges linking ten Mn ions together, leaving organized O6 end cavities capable of coordinating oxo-philic cations.

Graphical abstract: Approaching polymetallic ‘Assemblies of Assemblies’ using ligands with multiple functionality – novel Mn10M2 (M = alkali metal) chains with ‘ionophoric’ end cavities

Supplementary files

Article information

Article type
Communication
Submitted
07 Jun 2011
Accepted
21 Jun 2011
First published
15 Jul 2011

Dalton Trans., 2011,40, 8079-8082

Approaching polymetallic ‘Assemblies of Assemblies’ using ligands with multiple functionality – novel Mn10M2 (M = alkali metal) chains with ‘ionophoric’ end cavities

M. U. Anwar, L. N. Dawe and L. K. Thompson, Dalton Trans., 2011, 40, 8079 DOI: 10.1039/C1DT11067E

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