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Issue 33, 2011
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Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

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Abstract

Unsaturated σ,π-cyclooctenyl and hydrido Ir(III) complexes bearing an unusual tridentate dianionic ONO pincer-type ligand have been straightforwardly obtained from 2,6-pyridinedicarboxylic acid and standard Ir(I) starting materials. These complexes efficiently catalyzed the arene C–H borylation under thermal conditions.

Graphical abstract: Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

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Publication details

The article was received on 06 Apr 2011, accepted on 03 Jun 2011 and first published on 21 Jul 2011


Article type: Paper
DOI: 10.1039/C1DT11046B
Citation: Dalton Trans., 2011,40, 8429-8435

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    Unsaturated iridium pyridinedicarboxylate pincer complexes with catalytic activity in borylation of arenes

    D. Hanh Nguyen, J. J. Pérez-Torrente, L. Lomba, M. Victoria Jiménez, F. J. Lahoz and L. A. Oro, Dalton Trans., 2011, 40, 8429
    DOI: 10.1039/C1DT11046B

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