Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P4 ligand

Vincenzo Mirabello; Maria Caporali; Vito Gallo; Luca Gonsalvi; Andrea Ienco; Mario Latronico; Piero Mastrorilli; Maurizio Peruzzini

doi:10.1039/C1DT10572H

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Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P₄ ligand†

Vincenzo Mirabello,^a Maria Caporali,^a Vito Gallo,^b Luca Gonsalvi,^a Andrea Ienco,^a Mario Latronico,^b Piero Mastrorilli^b and Maurizio Peruzzini*^a

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* Corresponding authors

^a Consiglio Nazionale delle Ricerche, Istituto di Chimica dei Composti Organometallici (ICCOM-CNR), Via Madonna del Piano 10, Sesto Fiorentino, Firenze, Italy
E-mail: maurizio.peruzzini@iccom.cnr.it
Fax: ++39 055 5225203
Tel: ++39 055 5225289

^b Dipartimento di Ingegneria delle Acque e di Chimica, Politecnico di Bari, Via Orabona 4, Bari, Italy

Abstract

Dynamic processes involving the P₄ cage coordinated to transition metal fragments were observed for the mononuclear complex trans-[Ru(dppm)₂(H)(η¹-P₄)]BF₄ and for the bimetallic derivative trans-[Ru(dppm)₂(H)(μ ,η^1:2-P₄){Pt(PPh₃)₂}]BF₄ as demonstrated by NMR experiments and DFT calculations.

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Article information

DOI: https://doi.org/10.1039/C1DT10572H
Article type: Communication
Submitted: 04 Apr 2011
Accepted: 27 Jul 2011
First published: 24 Aug 2011

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Dalton Trans., 2011,40, 9668-9671

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Dynamic behaviour of Ru and Ru–Pt complexes containing tetrahedro-P₄ ligand

V. Mirabello, M. Caporali, V. Gallo, L. Gonsalvi, A. Ienco, M. Latronico, P. Mastrorilli and M. Peruzzini, Dalton Trans., 2011, 40, 9668 DOI: 10.1039/C1DT10572H

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