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Issue 25, 2011
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Thermal isomerization of η6-arene ferradicarbolllides. Experimental proof for isolobal relation between (η6-arene)Fe and (η5-cyclopentadienyl)Co cluster units

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Abstract

The heating of selected [1-(η6-arene)-closo-1,2,3-FeC2B9H11] complexes resulted in the thermal rearrangement and isolation of the corresponding 1,2,4-, 1,2,7-, and 1,2,8-cage isomers. Demonstrated here is a similar rearrangement and the NMR behaviour for isostructural [1-(η5-cyclopentadienyl)-closo-1,2,3-CoC2B9H11] compounds

Graphical abstract: Thermal isomerization of η6-arene ferradicarbolllides. Experimental proof for isolobal relation between (η6-arene)Fe and (η5-cyclopentadienyl)Co cluster units

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Article information


Submitted
03 Mar 2011
Accepted
21 Apr 2011
First published
17 May 2011

Dalton Trans., 2011,40, 6623-6625
Article type
Communication

Thermal isomerization of η6-arene ferradicarbolllides. Experimental proof for isolobal relation between (η6-arene)Fe and (η5-cyclopentadienyl)Co cluster units

J. Holub, B. Štíbr, M. Bakardjiev, A. Růžička and Z. Padělková, Dalton Trans., 2011, 40, 6623
DOI: 10.1039/C1DT10367A

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