Issue 25, 2011
From the journal:

Dalton Transactions

A divalent germanium complex of calix[5]arene†

Aaron C. Schrick,a   Arnold L. Rheingoldb  and  Charles S. Weinert*a  

* Corresponding authors

a Department of Chemistry, Oklahoma State University, Stillwater, Oklahoma, (USA)
E-mail: Weinert@chem.okstate.edu
Fax: (405) 744-6007

b Department of Chemistry and Biochemistry, University of California-San Diego, La Jolla, CA, (USA)

Abstract

The reaction of the germylene Ge[N(SiMe3)2]2 with calix[5]arene yields the first example of a group 14 calix[5]arene complex. The crystal structure of this material has been obtained and contains two calix[5]arene macrocycles held together by a Ge2O2 rhombus.

Graphical abstract: A divalent germanium complex of calix[5]arene

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Article information

DOI
https://doi.org/10.1039/C1DT10347D
Article type
Communication
Submitted
01 Mar 2011
Accepted
06 May 2011
First published
26 May 2011

Dalton Trans., 2011,40, 6629-6631

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A divalent germanium complex of calix[5]arene

A. C. Schrick, A. L. Rheingold and C. S. Weinert, Dalton Trans., 2011, 40, 6629 DOI: 10.1039/C1DT10347D

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