Issue 20, 2011
From the journal:

Dalton Transactions

Mn(C2O4)(H2O)0.25: an antiferromagnetic oxalato-based cage compound†

Bin Zhang,*a   Yan Zhang,b   Jinbiao Zhang,a   Xiang Haoc  and  Daoben Zhu*a  

* Corresponding authors

a BNLMS, Organic Solid Laboratory, CMS & Institute of Chemistry, Chinese Academy of Science, Beijing, P. R. China
E-mail: zhangbin@iccas.ac.cn, zhudb@iccas.ac.cn
Fax: +86 10-62559373
Tel: +86 10-62558982

b Department of Physics, Peking University, Beijing, P. R. China

c Centre for Physiochemical Analysis and Measurement, CMS & Institute of Chemistry, Chinese Academy of Science, Beijing, P. R. China

Abstract

An oxalato-based cage compound Mn(C2O4)(H2O)0.25 was obtained using a solvothermal method. Mn is pentagonal bipyramidal coordinated with O from oxalato with three-atom and one-atom bridges. There are hydrogen bonds between the framework and clathrated H2O. A 3D long-range magnetic ordering was observed at 10.9 K.

Graphical abstract: Mn(C2O4)(H2O)0.25: an antiferromagnetic oxalato-based cage compound

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Article information

DOI
https://doi.org/10.1039/C1DT10346F
Article type
Communication
Submitted
01 Mar 2011
Accepted
30 Mar 2011
First published
18 Apr 2011

Dalton Trans., 2011,40, 5430-5432

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Mn(C2O4)(H2O)0.25: an antiferromagnetic oxalato-based cage compound

B. Zhang, Y. Zhang, J. Zhang, X. Hao and D. Zhu, Dalton Trans., 2011, 40, 5430 DOI: 10.1039/C1DT10346F

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