Issue 33, 2011
From the journal:

Dalton Transactions

Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde†

Huaqiao Tan,a   Weilin Chen,a   Ding Liu,a   Xiaojia Feng,a   Yangguang Li,*a   Aixue Yana  and  Enbo Wang*a  

* Corresponding authors

a Key Laboratory of Polyoxometalate Science of Ministry of Education Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, P. R. China
E-mail: wangeb889@nenu.edu.cn, liyg658@nenu.edu.cn
Fax: +86-431-85098787
Tel: +86-431-85098787

Abstract

Two asymmetric polyoxomolybdates Na6{Mo2O5[(Mo2O6)NH3CH2CH2CH2C(O)(PO3)2]2}·16H2O (1) and (NH4)7Na{MoO2[(Mo2O6)NH3CH2CH2CH2C(O)(PO3)2]}4·H2O (2) have been synthesized by the reactions of alendronic acid with molybdate. Structure analysis revealed that the polyoxoanions 1 and 2 can be described as dimeric and tetrameric aggregates of the {MoO3[(Mo2O6)NH3CH2CH2CH2C(O)(PO3)2]} units respectively. Their tetrabutylammonium salts show efficient selective oxidation of benzyl alcohol to benzaldehyde with 72.5% and 81.5% benzyl alcohol conversion, and 87.1% and 82.4% benzaldehyde selectivity, respectively.

Graphical abstract: Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0DT01729A
Article type
Paper
Submitted
09 Dec 2010
Accepted
10 Jun 2011
First published
19 Jul 2011

Dalton Trans., 2011,40, 8414-8418

Permissions

Request permissions

Two diphosphonate-functionalized asymmetric polyoxomolybdates with catalytic activity for oxidation of benzyl alcohol to benzaldehyde

H. Tan, W. Chen, D. Liu, X. Feng, Y. Li, A. Yan and E. Wang, Dalton Trans., 2011, 40, 8414 DOI: 10.1039/C0DT01729A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements