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Issue 10, 2011
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Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: Completion of NO reduction cycle

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Abstract

The hydroxido-bridged dinuclear ruthenium complex 4, which is supported by Tp ligands, has been prepared from protonation of the oxido-bridged dinuclear ruthenium complex 3. Additional protonation of 4, affording the aqua-bridged dinuclear ruthenium complex 5in situ, and subsequent treatment with NO gave rise to the dicationic dinitrosyl complex 2. These indicate completion of the NO reduction cycle on the dinuclear ruthenium complex.

Graphical abstract: Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: Completion of NO reduction cycle

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Supplementary files

Article information


Submitted
12 Aug 2010
Accepted
14 Sep 2010
First published
13 Oct 2010

Dalton Trans., 2011,40, 2148-2150
Article type
Communication

Conversion of oxido-bridged dinuclear ruthenium complex to dicationic dinitrosyl ruthenium complex using proton and nitric oxide: Completion of NO reduction cycle

Y. Arikawa, N. Matsumoto, T. Asayama, K. Umakoshi and M. Onishi, Dalton Trans., 2011, 40, 2148 DOI: 10.1039/C0DT01002B

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