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Issue 25, 2010
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Transient chirality in a distal-substituted resorcinarene metal complex

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Abstract

A novel distal bidentate S/S resorcinarene ligand has been synthesised and a bis-μ-chloro-bridged palladium(II) complex obtained. The solid state structure for this complex represents the first crystal structure evidence for a bispalladium-μ-chloro-bridged complex bound to thioether ligands. Furthermore, solution NMR studies revealed conformational changes in the flexible resorcinarene ligand and discreet transient chirality around the sulfur centres.

Graphical abstract: Transient chirality in a distal-substituted resorcinarene metal complex

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Publication details

The article was received on 23 Apr 2010, accepted on 12 May 2010 and first published on 27 May 2010


Article type: Communication
DOI: 10.1039/C0DT00365D
Citation: Dalton Trans., 2010,39, 5780-5782

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    Transient chirality in a distal-substituted resorcinarene metal complex

    D. J. Kleinhans and G. E. Arnott, Dalton Trans., 2010, 39, 5780
    DOI: 10.1039/C0DT00365D

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