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Issue 43, 2010
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Studies in catalytic C–H amination involving nitrene C–H insertion

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Abstract

Stereoselective catalytic intermolecular C–H amination of complex molecules is reported. Site-selective functionalizations occur with very good yields up to 91% and excellent d.e.s up to 99%. However, the precise nature of the nitrene C–H insertion remains a matter of debate despite several physical organic experiments.

Graphical abstract: Studies in catalytic C–H amination involving nitrene C–H insertion

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Supplementary files

Article information


Submitted
09 Apr 2010
Accepted
21 Jun 2010
First published
08 Oct 2010

Dalton Trans., 2010,39, 10401-10413
Article type
Paper

Studies in catalytic C–H amination involving nitrene C–H insertion

F. Collet, C. Lescot, C. Liang and P. Dauban, Dalton Trans., 2010, 39, 10401 DOI: 10.1039/C0DT00283F

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