Issue 23, 2010
From the journal:

Dalton Transactions

Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies†

Miguel Rubio,a   Maxime A. Siegler,b   Anthony L. Spekb  and  Joost N. H. Reek*a  

* Corresponding authors

a Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, Amsterdam, (The Netherlands)
E-mail: j.n.h.reek@uva.nl
Fax: +31 20 5255604
Tel: +31 20 5255265

b Bijvoet Center for Biomolecular Research, Utrecht, (The Netherlands)
E-mail: a.l.spek@uu.nl
Fax: +31 30 2533940
Tel: +31 30 2532538

Abstract

New coordination polymers based on different combinations of silver atoms and pyridyl-substituted N-heterocyclic carbene moieties are described. The addition of Zn(II) templates leads to Ag–Zn supramolecular assemblies via selective Zn⋯N interactions; a process that can be reverted.

Graphical abstract: Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

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Article information

DOI
https://doi.org/10.1039/C003352A
Article type
Communication
Submitted
17 Feb 2010
Accepted
14 Apr 2010
First published
05 May 2010

Dalton Trans., 2010,39, 5432-5435

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Heterotopic silver–NHC complexes: from coordination polymers to supramolecular assemblies

M. Rubio, M. A. Siegler, A. L. Spek and J. N. H. Reek, Dalton Trans., 2010, 39, 5432 DOI: 10.1039/C003352A

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