Issue 18, 2010
From the journal:

Dalton Transactions

Hydrogen fluoride adduct of an ambiphilic phosphine–borane: NMR characterization and theoretical analysis of the bonding situation†

Sylvie Moebs-Sanchez,‡ab   Nathalie Saffon,c   Ghenwa Bouhadir,*ab   Laurent Maron*de  and  Didier Bourissou*ab  

* Corresponding authors

a Université de Toulouse, UPS, LHFA, 118 route de Narbonne, Toulouse, France

b CNRS, LHFA UMR 5069, Toulouse, France
E-mail: dbouriss@chimie.ups-tlse.fr
Fax: 33(0)5 6155 8204
Tel: 33(0)5 6155 7737

c Université Paul Sabatier, Structure Fédérative Toulousaine en Chimie Moléculaire (FR 2599), 118 route de Narbonne, Toulouse cedex 9, France

d Université de Toulouse, INSA, UPS, LPCNO, 135 avenue de Rangueil, Toulouse, France

e CNRS, LPCNO UMR 5215, Toulouse, France

Abstract

The HF adduct of the ambiphilic phosphine–borane [o-iPr2P(C6H4)BMes2] has been spectroscopically characterized and the nature of the interaction between the ensuing hydrogenophosphonium and fluoroborate moieties has been analyzed computationally.

Graphical abstract: Hydrogen fluoride adduct of an ambiphilic phosphine–borane: NMR characterization and theoretical analysis of the bonding situation

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Article information

DOI
https://doi.org/10.1039/C002068K
Article type
Paper
Submitted
01 Feb 2010
Accepted
16 Mar 2010
First published
29 Mar 2010

Dalton Trans., 2010,39, 4417-4420

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Hydrogen fluoride adduct of an ambiphilic phosphine–borane: NMR characterization and theoretical analysis of the bonding situation

S. Moebs-Sanchez, N. Saffon, G. Bouhadir, L. Maron and D. Bourissou, Dalton Trans., 2010, 39, 4417 DOI: 10.1039/C002068K

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