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Issue 9, 2010
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Heterotrimetallic 3d-4d-4f decanuclear metal-capped square showing single-molecule magnet behavior

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Abstract

The synthesis, the structural characterization and the magnetic properties of a heterotrimetallic decanuclear square, [(Mo(CN)8)2(CuLTb)4)]4+, noted MoCuTb, are described. This supramolecular compound, viewed as the first example of a metal-capped square, behaves as a single molecule magnet with a magnetic anisotropic barrier energy of Ueff = 13.40 cm−1 (19.25 K).

Graphical abstract: Heterotrimetallic 3d-4d-4f decanuclear metal-capped square showing single-molecule magnet behavior

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Publication details

The article was received on 28 Sep 2009, accepted on 02 Dec 2009 and first published on 06 Jan 2010


Article type: Communication
DOI: 10.1039/B924644B
Dalton Trans., 2010,39, 2188-2190

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    Heterotrimetallic 3d-4d-4f decanuclear metal-capped square showing single-molecule magnet behavior

    J. Long, L. Chamoreau and V. Marvaud, Dalton Trans., 2010, 39, 2188
    DOI: 10.1039/B924644B

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