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Issue 1, 2010
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Stepwise assembly of a bis-hydroxylaminato gallium–indium complex

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Abstract

A heterobimetallic galliumindium complex with five-coordinate InMe group bonded via two O and two N atoms to a [GaR2ON(Me)(CH2)2N(Me)O]2 macrocycle resulted from the reaction of the OH- and NH-functional bishydroxylaminato complex of gallium, MeN(OH)(CH2)2N(H)(Me)OGaR2O-cyclo[N(Me)(CH2)2N(Me)OGaR2] (R = tBu) with InMe3, whereas the reaction of the latter with Me3N·AlH3 affords a gallium hydride with Ga–Ga bonds.

Graphical abstract: Stepwise assembly of a bis-hydroxylaminato gallium–indium complex

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Article information


Submitted
01 Jul 2009
Accepted
14 Sep 2009
First published
24 Sep 2009

Dalton Trans., 2010,39, 66-69
Article type
Communication

Stepwise assembly of a bis-hydroxylaminato galliumindium complex

P. Bösing and N. W. Mitzel, Dalton Trans., 2010, 39, 66
DOI: 10.1039/B913016K

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