Issue 46, 2009

An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

Abstract

A chiral pseudo-C3-symmetric titanium triflate that employs the point chirality of a single stereogenic centre to control the propeller chirality of its aryl rings has been used to catalyse an asymmetric sulfoxidation reaction.

Graphical abstract: An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

Supplementary files

Article information

Article type
Communication
Submitted
26 Jun 2009
Accepted
16 Sep 2009
First published
05 Oct 2009

Dalton Trans., 2009, 10169-10171

An enantiopure pseudo-C3-symmetric titanium triflate with propeller-like chirality as a catalyst for asymmetric sulfoxidation reactions

P. Axe, S. D. Bull, M. G. Davidson, M. D. Jones, D. E. J. E. Robinson, W. L. Mitchell and J. E. Warren, Dalton Trans., 2009, 10169 DOI: 10.1039/B918141P

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