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Issue 35, 2009
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Unprecedented cubane-type silvercluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

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Abstract

A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag2I2 faces.

Graphical abstract: Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

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Article information


Submitted
11 Jun 2009
Accepted
16 Jul 2009
First published
04 Aug 2009

Dalton Trans., 2009, 7288-7293
Article type
Paper

Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand

M. Raynal, X. Liu, R. Pattacini, C. Vallée, H. Olivier-Bourbigou and P. Braunstein, Dalton Trans., 2009, 7288
DOI: 10.1039/B911439D

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