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Issue 17, 2009
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Synthesis and characterisation of Dewar benzeneferrocene conjugates

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Abstract

The first Dewar benzeneferrocene conjugates were synthesised by the reaction of tetraalkylcyclobutadiene–AlCl3 complexes with 3-ferrocenylpropynoates. Owing to extensive delocalisation, these conjugates feature unusually high thermal and chemical stability, rearranging to their corresponding phenylferrocenes (benzenes) under forcing microwave irradiation conditions.

Graphical abstract: Synthesis and characterisation of Dewar benzene–ferrocene conjugates

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Publication details

The article was received on 06 Feb 2009, accepted on 13 Mar 2009 and first published on 25 Mar 2009


Article type: Communication
DOI: 10.1039/B904488B
Dalton Trans., 2009, 3137-3139

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    Synthesis and characterisation of Dewar benzeneferrocene conjugates

    Š. Janková, I. Císařová, F. Uhlík, P. Štepnička and M. Kotora, Dalton Trans., 2009, 3137
    DOI: 10.1039/B904488B

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