Issue 36, 2009
From the journal:

Dalton Transactions

From 1D zigzag chain to 1D tubular structure, weak field ligand-dependent assembly of cucurbit[6]uril-based tubular coordination polymer†‡

Jing-Xin Liu,a   Chun-Hong Dong,a   La-Sheng Long,*a   Rong-Bin Huanga  and  Lan-Sun Zhenga  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: lslong@xmu.edu.cn
Fax: +86-592-2183047

Abstract

The reaction of cucurbit[6]uril with Cu(NO3)2 and CuCl2, respectively, generates a 1D zigzag chain of {[Cu(H2O)4(cucurbit[6]uril)]·(NO3)2·(H2O)8}n and a 1D tubular structure of {[Cu(H2O)2(Cl)2(cucurbit[6]uril)]1/3·(H2O)3}n, showing clearly how to control the reversible and mutual interconnections between ligand and metal ion under the guide of coordination chemistry.

Graphical abstract: From 1D zigzag chain to 1D tubular structure, weak field ligand-dependent assembly of cucurbit[6]uril-based tubular coordination polymer

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Article information

DOI
https://doi.org/10.1039/B904041B
Article type
Communication
Submitted
26 Feb 2009
Accepted
22 Jul 2009
First published
30 Jul 2009

Dalton Trans., 2009, 7344-7346

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From 1D zigzag chain to 1D tubular structure, weak field ligand-dependent assembly of cucurbit[6]uril-based tubular coordination polymer

J. Liu, C. Dong, L. Long, R. Huang and L. Zheng, Dalton Trans., 2009, 7344 DOI: 10.1039/B904041B

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