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Issue 12, 2009
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A non-classical copper carbonyl on a tri-alkene hydrocarbon support

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Abstract

Two rare copper complexes, a tri-alkene adduct [Cu(ttt-cdt)(FSbF5)] and a non-classical carbon monoxide complex [Cu(ttt-cdt)(CO)][SbF6] with a high CO stretching frequency ([small nu, Greek, macron]CO = 2160 cm−1), have been isolated using trans,trans,trans-1,5,9-cyclododecatriene (ttt-cdt) ligand.

Graphical abstract: A non-classical copper carbonyl on a tri-alkene hydrocarbon support

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Publication details

The article was received on 09 Feb 2009, accepted on 10 Feb 2009 and first published on 16 Feb 2009


Article type: Communication
DOI: 10.1039/B902678A
Dalton Trans., 2009, 2085-2087

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    A non-classical copper carbonyl on a tri-alkene hydrocarbon support

    M. Fianchini, T. R. Cundari, N. J. DeYonker and H. V. R. Dias, Dalton Trans., 2009, 2085
    DOI: 10.1039/B902678A

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