Metal fragment isomerisation upon grafting a d2 ML4perhydrocarbyl Os complex on a silica surface: origin and consequence†
Abstract
Grafting of Os bisalkylidene complexes, [Os(CHtBu)2(CH2tBu)2], on a silica partially dehydroxylated at 700 °C selectively yields an alkylidyne complex [(SiO)Os(CtBu)(CH2tBu)2] according to mass balance analysis,
- This article is part of the themed collection: The synergy between theory and experiment