Issue 6, 2009
From the journal:

Dalton Transactions

Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF3)2Tz)3]−†

Xiaodi Kou,a   Jiang Wu,a   Thomas R. Cundarib  and  H. V. Rasika Dias*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, Texas, USA
E-mail: dias@uta.edu

b Department of Chemistry, Center for Advanced Scientific Computing and Modeling (CASCaM), University of North Texas, Denton, Texas, USA

Abstract

Fluorinated tris(triazolyl)borate [HB(3,5-(CF3)2Tz)3]− (Tz = triazolyl) affords the isolation of [Na(THF)6]{[HB(3,5-(CF3)2Tz)3]2Na} with a ligand sandwiched sodium ion and a copper carbonyl complex [HB(3,5-(CF3)2Tz)3]CuCO with a high C–O stretching frequency.

Graphical abstract: Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF3)2Tz)3]−

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Article information

DOI
https://doi.org/10.1039/B819463G
Article type
Communication
Submitted
03 Nov 2008
Accepted
12 Nov 2008
First published
16 Dec 2008

Dalton Trans., 2009, 915-917

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Sandwiched sodium and half-sandwiched copper carbonyl complexes featuring polyfluorinated tris(triazolyl)borate [HB(3,5-(CF3)2Tz)3]−

X. Kou, J. Wu, T. R. Cundari and H. V. R. Dias, Dalton Trans., 2009, 915 DOI: 10.1039/B819463G

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