cis-Tach based pentadecadentate ligands as building blocks in the synthesis of FeIII and PdII coordination clusters

Graham N. Newton; Geoffrey J. T. Cooper; Dominik Schuch; Takuya Shiga; Sumit Khanra; De-Liang Long; Hiroki Oshio; Leroy Cronin

doi:10.1039/B815200D

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cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe^III and Pd^II coordination clusters†

Graham N. Newton,^a Geoffrey J. T. Cooper,^a Dominik Schuch,^a Takuya Shiga,^b Sumit Khanra,^a De-Liang Long,^a Hiroki Oshio^b and Leroy Cronin*^a

Author affiliations

* Corresponding authors

^a WestCHEM, Department of Chemistry, The University of Glasgow, University Avenue, Glasgow, UK
E-mail: L.Cronin@chem.gla.ac.uk
Fax: +44-141-330-4888
Tel: +44-141-330-6650

^b Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Japan
E-mail: oshio@chem.tsukuba.ac.jp
Fax: +81 29 853 4238
Tel: +81 29 853 4238

Abstract

A dodecanuclear Fe^III complex, consisting of two {Fe₆} units coupled across a single hydroxy-bridge and a cage-like Pd^II trimer were synthesised using the highly branched, pentadecadentate chelating ligand cis,cis-1,3,5-cyclohexanetriamine-N,N,N′,N′,N″,N″-hexaacetic acid (H₆hact).

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Supplementary files

Crystal structure data TXT (170K)

Article information

DOI: https://doi.org/10.1039/B815200D
Article type: Paper
Submitted: 01 Sep 2008
Accepted: 14 Nov 2008
First published: 26 Jan 2009

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Dalton Trans., 2009, 1549-1553

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cis-Tach based pentadecadentate ligands as building blocks in the synthesis of Fe^III and Pd^II coordination clusters

G. N. Newton, G. J. T. Cooper, D. Schuch, T. Shiga, S. Khanra, D. Long, H. Oshio and L. Cronin, Dalton Trans., 2009, 1549 DOI: 10.1039/B815200D

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Dalton Transactions