Issue 38, 2008
From the journal:

Dalton Transactions

[Bi5(dpd)6⊂CH3CN](ClO4)3·3CH3CN: a supramolecular, tetrahedral pentabismuth cluster derived from a nonabismuth oxo/hydroxide†

John H. Thurston,a   Michael J. Dougherty,a   Dale C. Swensona  and  Louis Messerle*a  

* Corresponding authors

a Department of Chemistry, The University of Iowa, Iowa City, IA, United States of America
E-mail: lou-messerle@uiowa.edu
Fax: +1 319 335-1270
Tel: +1 319 335-1372

Abstract

The novel tetrahedral [Bi5(dpd)6⊂CH3CN](ClO4)3·3CH3CN (dpd = di-2-pyridyl-gem-diolate) has been synthesized from [Bi9(μ3-O)8(μ3-OH)6](ClO4)5 and di-2-pyridyl ketone. The Bi5 complex incorporates CH3CN via C–H⋯O hydrogen bonding.

Graphical abstract: [Bi5(dpd)6⊂CH3CN](ClO4)3·3CH3CN: a supramolecular, tetrahedral pentabismuth cluster derived from a nonabismuth oxo/hydroxide

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Article information

DOI
https://doi.org/10.1039/B804044C
Article type
Communication
Submitted
18 Mar 2008
Accepted
04 Aug 2008
First published
27 Aug 2008

Dalton Trans., 2008, 5146-5148

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[Bi5(dpd)6⊂CH3CN](ClO4)3·3CH3CN: a supramolecular, tetrahedral pentabismuth cluster derived from a nonabismuth oxo/hydroxide

J. H. Thurston, M. J. Dougherty, D. C. Swenson and L. Messerle, Dalton Trans., 2008, 5146 DOI: 10.1039/B804044C

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