Issue 21, 2008
From the journal:

Dalton Transactions

o-Semiquinonic PCP-pincer nickel complexes with alkyl substituents: versatile coordination sphere dynamics†

Konstantin A. Kozhanov,*a   Michael P. Bubnov,a   Vladimir K. Cherkasov,a   Nina N. Vavilina,a   Larisa Yu. Efremova,a   Oleg. I. Artyushin,b   Irina L. Odinetsb  and  Gleb A. Abakumova  

* Corresponding authors

a G. A. Razuvaev Institute of Organometallic Chemistry of Russian Academy of Sciences, Tropinina str., 49, Nizhny Novgorod, Russia
E-mail: kostik@iomc.ras.ru
Fax: +7(831)4627497
Tel: +7(831)4627682

b A. N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Vavilova str. 28, Moscow, Russia
E-mail: odinets@ineos.ac.ru
Fax: 7(495)1355085

Abstract

o-Semiquinonic nickel pincer complexes (R2PCP)Ni(SQ) show a versatile coordination sphere dynamics via “swing” or “fan” oscillations depending on the steric properties of the phosphorus substituents.

Graphical abstract: o-Semiquinonic PCP-pincer nickel complexes with alkyl substituents: versatile coordination sphere dynamics

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Article information

DOI
https://doi.org/10.1039/B801350K
Article type
Paper
Submitted
24 Jan 2008
Accepted
10 Mar 2008
First published
07 Apr 2008

Dalton Trans., 2008, 2849-2853

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o-Semiquinonic PCP-pincer nickel complexes with alkyl substituents: versatile coordination sphere dynamics

K. A. Kozhanov, M. P. Bubnov, V. K. Cherkasov, N. N. Vavilina, L. Yu. Efremova, Oleg. I. Artyushin, I. L. Odinets and G. A. Abakumov, Dalton Trans., 2008, 2849 DOI: 10.1039/B801350K

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