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Issue 6, 2008
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Autocatalytic demetalation of a Zn(salphen) complex provoked by unprotected N-heterocycles

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Abstract

The interaction of Zn(salphen) complex 1a with biologically important structures such as (benz)imidazoles and purine has been studied and revealed in the case of unprotected purine and (benz)imidazole derivatives a demetalated product, whereas for structurally related 1-methyl-(benz)imidazole the formation of 1 : 1 coordination complexes was evidenced by NMR, MS and X-ray crystallography.

Graphical abstract: Autocatalytic demetalation of a Zn(salphen) complex provoked by unprotected N-heterocycles

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Article information


Submitted
24 Aug 2007
Accepted
09 Nov 2007
First published
23 Nov 2007

Dalton Trans., 2008, 734-737
Article type
Communication

Autocatalytic demetalation of a Zn(salphen) complex provoked by unprotected N-heterocycles

E. C. Escudero-Adán, J. Benet-Buchholz and A. W. Kleij, Dalton Trans., 2008, 734
DOI: 10.1039/B713039B

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