Issue 38, 2007
From the journal:

Dalton Transactions

C–H activation motivated by N,N′-diisopropylcarbodiimide within a lutetium complex stabilized by an amino–phosphine ligand†‡

Bo Liu,ab   Yi Yang,ab   Dongmei Cui,*a   Tao Tang,a   Xuesi Chena  and  Xiabin Jinga  

* Corresponding authors

a State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Science, 5625 Renmin street, Changchun, China
E-mail: dmcui@ciac.ji.cn
Fax: +86 431 8526 2773
Tel: +86 431 8526 2773

b Graduate School of Chinese Academy of Sciences, Beijing, China

Abstract

A lutetium bis(alkyl) complex stabilized by a flexible amino–phosphine ligand LLu(CH2Si(CH3)3)2(THF) (L = (2,6-C6H3(CH3)2)NCH(C6H5)CH2P(C6H5)2) was prepared which upon insertion of N,N′-diisopropylcarbodiimide led to C–H activation via metalation of the ligand aryl methyl followed by reduction of the C[double bond, length as m-dash]N double bond.

Graphical abstract: C–H activation motivated by N,N′-diisopropylcarbodiimide within a lutetium complex stabilized by an amino–phosphine ligand

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Article information

DOI
https://doi.org/10.1039/B710039F
Article type
Communication
Submitted
02 Jul 2007
Accepted
06 Jul 2007
First published
25 Jul 2007

Dalton Trans., 2007, 4252-4254

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C–H activation motivated by N,N′-diisopropylcarbodiimide within a lutetium complex stabilized by an amino–phosphine ligand

B. Liu, Y. Yang, D. Cui, T. Tang, X. Chen and X. Jing, Dalton Trans., 2007, 4252 DOI: 10.1039/B710039F

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