Issue 48, 2007
From the journal:

Dalton Transactions

The first 1D twofold interpenetrating metal–organic network generated by 1D triple helical chains with nanosized cages†‡§

Cao-Yuan Niu,ab   Ben-Lai Wu,a   Xian-Fu Zheng,b   Hong-Yun Zhang,*a   Zhong-Jun Lia  and  Hong-Wei Houa  

* Corresponding authors

a Department of Chemistry, Zhengzhou University, Zhengzhou, P. R. China
E-mail: wzhy917@zzu.edu.cn
Fax: +86 371 67763675
Tel: +86 371 67763675

b College of Sciences, Henan Agricultural University, Zhengzhou, P. R. China
Fax: +86 371 63554576
Tel: +371 63554576

Abstract

Reaction of AgPF6 with the asymmetric ligand 1,6-dihydro-2-methyl-6-oxo-(3,4′-bipyridine)-5-carbonitrile (1), afforded a significant silver coordination polymer {[Ag2(1)3]2·(CH3OH)3·(PF6)4}n (2) with unique 1D twofold interpenetrating metal–organic frameworks constructed by 1D triple helical chains with nanosized cages hosting counterions as guests. This compound exhibits high thermal stability and blue-shift emission with large intensity enhancement compared with that of the free ligand.

Graphical abstract: The first 1D twofold interpenetrating metal–organic network generated by 1D triple helical chains with nanosized cages

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Article information

DOI
https://doi.org/10.1039/B709204K
Article type
Paper
Submitted
18 Jun 2007
Accepted
27 Sep 2007
First published
11 Oct 2007

Dalton Trans., 2007, 5710-5713

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The first 1D twofold interpenetrating metal–organic network generated by 1D triple helical chains with nanosized cages

C. Niu, B. Wu, X. Zheng, H. Zhang, Z. Li and H. Hou, Dalton Trans., 2007, 5710 DOI: 10.1039/B709204K

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