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Issue 30, 2007
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[VIV15SbIII6O42]6−: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6−

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Abstract

A hydrothermal approach employing an amine as reducing agent enables synthesis of an analogue of the arsenato(III)-oxovanadate {V15As6}, representing the first systematic variation of this intensely studied magnetic system.

Graphical abstract: [VIV15SbIII6O42]6−: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6−

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Publication details

The article was received on 08 Jun 2007, accepted on 18 Jun 2007 and first published on 06 Jul 2007


Article type: Communication
DOI: 10.1039/B708744F
Dalton Trans., 2007, 3221-3223

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    [VIV15SbIII6O42]6−: An antimony analogue of the molecular magnet [V15As6O42(H2O)]6−

    R. Kiebach, C. Näther, P. Kögerler and W. Bensch, Dalton Trans., 2007, 3221
    DOI: 10.1039/B708744F

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