Issue 37, 2007
From the journal:

Dalton Transactions

Microwave-assisted hydrothermal syntheses of metal phosphonates with layered and framework structures†

Yi-Fan Yang,a   Yun-Sheng Ma,a   Song-Song Baoa  and  Li-Min Zheng*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, P. R. China
E-mail: lmzheng@netra.nju.edu.cn
Fax: +86-25-83314502

Abstract

Under microwave-assisted hydrothermal conditions, two new compounds Zn(pinH)(H2O) (1) and Cd(pinH) (2) have been obtained through the reactions of zinc (or cadmium) sulfate and 2-phosphonic-isonicotinic acid (pinH3). The former has a layer structure in which double chains composed of corner-sharing {ZnO5N} octahedra and {CPO3} tetrahedra are cross-linked through the carboxylate groups. The latter has a framework structure where the inorganic layers composed of edge-sharing {CdO5N} octahedra and {CPO3} tetrahedra are pillared by the pyridyl carboxylate groups.

Graphical abstract: Microwave-assisted hydrothermal syntheses of metal phosphonates with layered and framework structures

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Article information

DOI
https://doi.org/10.1039/B708688A
Article type
Paper
Submitted
07 Jun 2007
Accepted
31 Jul 2007
First published
13 Aug 2007

Dalton Trans., 2007, 4222-4226

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Microwave-assisted hydrothermal syntheses of metal phosphonates with layered and framework structures

Y. Yang, Y. Ma, S. Bao and L. Zheng, Dalton Trans., 2007, 4222 DOI: 10.1039/B708688A

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