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Issue 28, 2007
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Low temperature in situ UV irradiation of [(η5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(iii) silyl hydride complexes

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Abstract

Low temperature in situ UV irradiation of [(η5-C5H5)Co(C2H4)2] in the presence of silanes enables the characterisation of unstable fluxional Co(III) silyl hydride complexes [(η5-C5H5)Co(SiR3)(H)(C2H4)] (SiR3 = SiEt3, SiMe3 or SiHEt2) by NMR spectroscopy; the reaction of [Co(η5-C5H5)(C2H4)2] with HSiR3 proceeds thermally to reach an equilibrium when SiR3 = Si(OMe)3 or SiClMePh.

Graphical abstract: Low temperature in situ UV irradiation of [(η5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(iii) silyl hydride complexes

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Article information


Submitted
10 Apr 2007
Accepted
10 May 2007
First published
31 May 2007

Dalton Trans., 2007, 2993-2996
Article type
Communication

Low temperature in situ UV irradiation of [(η5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(III) silyl hydride complexes

K. A. M. Ampt, S. B. Duckett and R. N. Perutz, Dalton Trans., 2007, 2993
DOI: 10.1039/B705290A

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