Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate†
Abstract
The synthesis, structure and magnetic properties of [Mn13O8(OEt)6(O2CC6H4OPh)12] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S6 symmetry and an S = 11/2 ground state.