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Issue 9, 2007
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Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

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Abstract

Redox active polyiron complexes with higher dimensional spacers, the tetrairon complex with the two-dimensional tetra(ethynylphenyl)ethene spacer, (C[double bond, length as m-dash]C)[p-C6H4–C[triple bond, length as m-dash]C–FeCp*(dppe)]4, and the diiron complex with the three-dimensional spacer (pseudo-m-[2,2]paracyclophane)[C[triple bond, length as m-dash]C–FeCp*(dppe)]2, are prepared, and their performance as molecular wires is evaluated on the basis of their comproportionation constants for the mixed valence state.

Graphical abstract: Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

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Article information


Submitted
11 Oct 2006
Accepted
02 Jan 2007
First published
18 Jan 2007

Dalton Trans., 2007, 928-933
Article type
Paper

Redox-active polyiron complexes with tetra(ethynylphenyl)ethene and [2,2]paracyclophane spacers containing ethynylphenyl units: extension to higher dimensional molecular wire

Y. Tanaka, T. Ozawa, A. Inagaki and M. Akita, Dalton Trans., 2007, 928
DOI: 10.1039/B614803D

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