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Issue 27, 2006
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Carbene or zwitterion? Competition in organoplatinum complexes

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Abstract

The reaction of a known dimeric dicarbene complex of platinum with a number of ligands results in four new platinum complexes. The structure of the new complexes is described: one complex must exist as a neutral complex with no charge separation, and the other three are assigned a charge-separated (zwitterionic) structure, rather than a carbene form, on the basis of comparative 13C NMR shifts.

Graphical abstract: Carbene or zwitterion? Competition in organoplatinum complexes

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Publication details

The article was received on 20 Dec 2005, accepted on 06 Apr 2006 and first published on 13 Apr 2006


Article type: Paper
DOI: 10.1039/B517874F
Dalton Trans., 2006, 3321-3325

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    Carbene or zwitterion? Competition in organoplatinum complexes

    C. P. Newman, G. J. Clarkson, N. W. Alcock and J. P. Rourke, Dalton Trans., 2006, 3321
    DOI: 10.1039/B517874F

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