Issue 2, 2005
From the journal:

Dalton Transactions

Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

Jens Brunner,a   Hans Pritzkowa  and  Roland Krämera  

a University of Heidelberg, Im Neuenheimer Feld 275, Heidelberg, Germany
E-mail: Roland.Kraemer@urz.uni-heidelberg.de
Fax: +49 6221/487 672

Abstract

The synthesis of the new ligand L1 (H4L1 = 3,8,16,21-tetrakis(carboxylmethyl)-3,8,16,21,27,28-hexaazatricyclo[21.3.1.110,14]octacosa-1(27),10,12,14(28),23,25-hexaen-5,18-diine) is reported. The solid-state structures of the four homodinuclear chelate complexes, [Zn2(L1)(H2O)2]·6H2O, [Fe2(L1)(µ-O)]·4H2O, [La2(L1)(NO3)2(H2O)2]·6H2O and Na[Eu2(L1)(µ-AcO)3] ·3H2O, were determined by single-crystal X-ray structural analysis

Graphical abstract: Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

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Article information

DOI
https://doi.org/10.1039/B412775G
Article type
Paper
Submitted
19 Aug 2004
Accepted
24 Nov 2004
First published
06 Dec 2004

Dalton Trans., 2005, 338-343

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Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

J. Brunner, H. Pritzkow and R. Krämer, Dalton Trans., 2005, 338 DOI: 10.1039/B412775G

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