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Issue 2, 2005
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Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

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Abstract

The synthesis of the new ligand L1 (H4L1 = 3,8,16,21-tetrakis(carboxylmethyl)-3,8,16,21,27,28-hexaazatricyclo[21.3.1.110,14]octacosa-1(27),10,12,14(28),23,25-hexaen-5,18-diine) is reported. The solid-state structures of the four homodinuclear chelate complexes, [Zn2(L1)(H2O)2]·6H2O, [Fe2(L1)(µ-O)]·4H2O, [La2(L1)(NO3)2(H2O)2]·6H2O and Na[Eu2(L1)(µ-AcO)3] ·3H2O, were determined by single-crystal X-ray structural analysis

Graphical abstract: Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

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Publication details

The article was received on 19 Aug 2004, accepted on 24 Nov 2004 and first published on 06 Dec 2004


Article type: Paper
DOI: 10.1039/B412775G
Dalton Trans., 2005, 338-343

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    Synthesis of a novel dinucleating aminocarboxylate macrocycle and structures of its dinuclear complexes with di- and trivalent transition and lanthanide metal ions

    J. Brunner, H. Pritzkow and R. Krämer, Dalton Trans., 2005, 338
    DOI: 10.1039/B412775G

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