Issue 20, 2004

Anomalous structure–luminescence relationship in phosphorescent gold(i) isonitrile neutral complexes

Abstract

A new compound that exhibits the shortest intermolecular Au⋯Au distance ever reported for neutral RNCAuX complexes is found to exhibit a counterintuitive higher-energy Au-centered phosphorescence than that in an analogous compound with a much longer Au⋯Au distance, presumably due to a different extent of excited-state distortion in dimers vs. extended chains.

Graphical abstract: Anomalous structure–luminescence relationship in phosphorescent gold(i) isonitrile neutral complexes

Article information

Article type
Communication
Submitted
13 Jul 2004
Accepted
25 Aug 2004
First published
07 Sep 2004

Dalton Trans., 2004, 3173-3175

Anomalous structure–luminescence relationship in phosphorescent gold(I) isonitrile neutral complexes

O. Elbjeirami, M. A. Omary, M. Stender and A. L. Balch, Dalton Trans., 2004, 3173 DOI: 10.1039/B410657A

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