Synthesis and structural characterization of two novel heterometallic clusters: [Rh4Pt2(CO)11(dppm)2] and [Ru2Rh2Pt2(CO)12(dppm)2]†
Abstract
Two novel heterometallic octahedral clusters [Rh4Pt2(CO)11(dppm)2]
(1) and [Ru2Rh2Pt2(CO)12(dppm)2]
(2) were synthesized by the reaction of [Rh2Pt2(CO)6(dppm)2] with [Rh6(CO)14(NCMe)2] and Ru3(CO)12, respectively. Solid state structures of 1 and 2 have been established by a