Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(i)
Abstract
A series of carbene complexes RhCl(CR′2)(PR3)2
(R = Ph, Tol, Me, R′
= Ph and Tol) have been synthesised through direct reaction of photochemically generated free diarylcarbene with RhCl(CO)(PR3)2. This route to