Issue 12, 2004
From the journal:

Dalton Transactions

Novel unsymmetrical P/O substituted ferroceneligands and the first structurally characterised hydroxyferrocene derivative†

Robert C. J. Atkinson,a   Vernon C. Gibson,*a   Nicholas J. Long,*a   Andrew J. P. Whitea  and  David J. Williamsa  

* Corresponding authors

a Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ
E-mail: n.long@imperial.ac.uk
Fax: +44 (0)20 7594 5804
Tel: +44 (0)20 7594 5781

Abstract

Two new unsymmetrical 1′-substituted hydroxyferrocene ligands featuring either phosphine or phosphine oxide substituents have been synthesised and the phosphine oxide derivative has been structurally characterised. A nickel complex of the hydroxyl/phosphine ligand has been formed, along with preliminary evaluation of the complex for catalysis of ethylene polymerisation.

Graphical abstract: Novel unsymmetrical P/O substituted ferrocene ligands and the first structurally characterised hydroxyferrocene derivative

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Article information

DOI
https://doi.org/10.1039/B403862B
Article type
Paper
Submitted
12 Mar 2004
Accepted
05 May 2004
First published
19 May 2004

Dalton Trans., 2004, 1823-1826

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Novel unsymmetrical P/O substituted ferrocene ligands and the first structurally characterised hydroxyferrocene derivative

R. C. J. Atkinson, V. C. Gibson, N. J. Long, A. J. P. White and D. J. Williams, Dalton Trans., 2004, 1823 DOI: 10.1039/B403862B

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