Issue 8, 2004
From the journal:

Dalton Transactions

PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex†

Piero Mastrorilli,*a   Mario Latronico,b   Cosimo Francesco Nobile,a   Gian Paolo Suranna,a   Francesco Paolo Fanizzi,c   Ulli Englertd  and  Giuseppe Ciccarellae  

* Corresponding authors

a Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari, via Orabona 4, I-70125 Bari, Italy
E-mail: p.mastrorilli@poliba.it
Fax: +39 080 5963611
Tel: +39 080 5963605

b D. I. F. A., Università della Basilicata, Viale dell'Università 10, I-85100 Potenza, Italy

c Dip. di Scienze e Tecnologie Biologiche e Ambientali, Università di Lecce, Via Monteroni, I-73100, Lecce, Italy

d Institut für Anorganische Chemie der RWTH, Prof. Pirlet Str., 1 D-52074 Aachen, Germany

e Dipartimento di Ingegneria dell'Innovazione, University of Lecce, Via Monteroni, I-73100, Lecce, Italy

Abstract

Exposure of solid trans-[Pt(PHCy2)2(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2){(PCy2O)2H}] (2) as the major product, the formation of which has been followed by NOESY 1H NMR techniques.

Graphical abstract: PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex

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Article information

DOI
https://doi.org/10.1039/B402180K
Article type
Communication
Submitted
12 Feb 2004
Accepted
04 Mar 2004
First published
19 Mar 2004

Dalton Trans., 2004, 1117-1119

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PtCl(PHCy2){(PCy2O)2H}: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex

P. Mastrorilli, M. Latronico, C. F. Nobile, G. P. Suranna, F. P. Fanizzi, U. Englert and G. Ciccarella, Dalton Trans., 2004, 1117 DOI: 10.1039/B402180K

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