A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20− anion
Abstract
The non-cyclic polyoxo(thio)molybdate(V)-sulfite K6(NH4)14{[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}·7H2O 1 was prepared by self-condensation of [Mo2V(μ-S)2O2]2+ building block in the presence of (NH4)2SO3. Compound 1 was characterized by X-ray structure analysis as well as