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Issue 19, 2003
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A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}20− anion

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Abstract

The non-cyclic polyoxo(thio)molybdate(V)-sulfite K6(NH4)14{[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}·7H2O 1 was prepared by self-condensation of [Mo2V(μ-S)2O2]2+ building block in the presence of (NH4)2SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

Graphical abstract: A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20− anion

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Publication details

The article was received on 07 Aug 2003, accepted on 15 Aug 2003 and first published on 21 Aug 2003


Article type: Communication
DOI: 10.1039/B309473C
Citation: Dalton Trans., 2003,0, 3668-3670

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    A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}20− anion

    H. N. Miras, J. Derek Woollins, A. M. Slawin, R. Raptis, P. Baran and T. A. Kabanos, Dalton Trans., 2003, 0, 3668
    DOI: 10.1039/B309473C

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