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Issue 19, 2003
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A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}20− anion

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Abstract

The non-cyclic polyoxo(thio)molybdate(V)-sulfite K6(NH4)14{[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}·7H2O 1 was prepared by self-condensation of [Mo2V(μ-S)2O2]2+ building block in the presence of (NH4)2SO3. Compound 1 was characterized by X-ray structure analysis as well as IR, UV-vis spectroscopies and thermogravimetric analysis.

Graphical abstract: A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]6(μ3-SO3)4(μ-SO3)12}20− anion

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Article information


Submitted
07 Aug 2003
Accepted
15 Aug 2003
First published
21 Aug 2003

Dalton Trans., 2003, 3668-3670
Article type
Communication

A novel polyoxo(thio)molybdenum(V) sulfite compound: Synthesis and crystal structure of {[Mo2V(μ-S)2O2]63-SO3)4(μ-SO3)12}20− anion

H. N. Miras, J. Derek Woollins, A. M. Slawin, R. Raptis, P. Baran and T. A. Kabanos, Dalton Trans., 2003, 3668
DOI: 10.1039/B309473C

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