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Issue 19, 2003
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Synthesis, structural and theoretical studies of an iron–gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

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Abstract

The first iron complex of an anionic gallium N-heterocyclic carbene analogue, [Fe(CO)4{Ga[N(Ar)C(H)]2}] Ar = C6H3Pri2-2,6, has been prepared and shown to have an unusual polymeric structure in the solid state; theoretical studies have pointed toward minimal Fe → Ga back-bonding in this complex.

Graphical abstract: Synthesis, structural and theoretical studies of an iron–gallium(i) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

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Publication details

The article was received on 23 Jul 2003, accepted on 26 Aug 2003 and first published on 28 Aug 2003


Article type: Communication
DOI: 10.1039/B308616J
Citation: Dalton Trans., 2003,0, 3673-3674

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    Synthesis, structural and theoretical studies of an iron–gallium(I) heterocycle complex: Analogies with N-heterocyclic carbene chemistry

    R. J. Baker, C. Jones and J. A. Platts, Dalton Trans., 2003, 0, 3673
    DOI: 10.1039/B308616J

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