Issue 14, 2003
From the journal:

Dalton Transactions

Vanadium complexes incorporating the β-diketiminato ligand L. Syntheses and structures of LV(OSO2CF3)2 and LVPPh2

Dante Neculai,a   Ana Mirela Neculai,a   Herbert W. Roesky,*a   Regine Herbst-Irmer,a   Bernhard Walfortb  and  Dietmar Stalkeb  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Göttingen, Tammannstr. 4, D-37077, Göttingen, Germany
E-mail: hroesky@gwdg.de
Fax: +49-551-393373
Tel: +49-551-393001

b Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-97074, Würzburg, Germany

Abstract

The reaction of LLi (where L = N,N′-bis(2-diethylaminoethyl)-2,4-pentanediimine-ate(-1)) with VCl3·3THF yielded LVCl2, which was characterized by EI-MS and elemental analysis. Subsequent reactions of LVCl2 with AgOSO2CF3 and KPPh2 afforded two new complexes, LV(OSO2CF3)2 and LVPPh2 which were characterized by 19F, 31P NMR spectroscopy, EI-MS, elemental analysis, and single crystal X-ray structural analysis.

Graphical abstract: Vanadium complexes incorporating the β-diketiminato ligand L. Syntheses and structures of LV(OSO2CF3)2 and LVPPh2

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Article information

DOI
https://doi.org/10.1039/B303196A
Article type
Paper
Submitted
20 Mar 2003
Accepted
04 Jun 2003
First published
23 Jun 2003

Dalton Trans., 2003, 2831-2834

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Vanadium complexes incorporating the β-diketiminato ligand L. Syntheses and structures of LV(OSO2CF3)2 and LVPPh2

D. Neculai, A. Mirela Neculai, H. W. Roesky, R. Herbst-Irmer, B. Walfort and D. Stalke, Dalton Trans., 2003, 2831 DOI: 10.1039/B303196A

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