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Issue 14, 2003
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Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

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Abstract

Supramolecular complexes of tetra-p-sulfonatocalix[4]arene and (S)-serine have been isolated in the solid state and their molecular structures elucidated by X-ray diffraction studies. Chiral pairs of (S)-serine molecules are confined in ‘capsules’ of tetra-p-sulfonatocalix[4]arene in an overall bilayer arrangement. Complexes containing differing amounts of sodium and caesium cations are reported.

Graphical abstract: Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

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Article information


Submitted
03 Feb 2003
Accepted
23 May 2003
First published
12 Jun 2003

Dalton Trans., 2003, 2923-2927
Article type
Paper

Confinement of (S)-serine in tetra-p-sulfonatocalix[4]arene bilayers

P. J. Nichols and C. L. Raston, Dalton Trans., 2003, 2923
DOI: 10.1039/B301316B

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