Issue 7, 2002

Phenoxyl radical FeIII complex of cis,cis-1,3,5-tris(3′,5′-di-tert-butylsalicylaldimino)cyclohexane, spectro-electrochemical and structural studies

Abstract

Complexation of cis,cis-1,3,5-tris(3′,5′-di-tert-butylsalicylaldimino)cyclohexane (H3tBu2saltach) with MIII (M = Fe and Ga) followed by subsequent one electron oxidation results in the formation of stable phenoxyl-radical complexes.

Graphical abstract: Phenoxyl radical FeIII complex of cis,cis-1,3,5-tris(3′,5′-di-tert-butylsalicylaldimino)cyclohexane, spectro-electrochemical and structural studies

Supplementary files

Article information

Article type
Communication
Submitted
17 Jan 2002
Accepted
26 Feb 2002
First published
08 Mar 2002

J. Chem. Soc., Dalton Trans., 2002, 1253-1255

Phenoxyl radical FeIII complex of cis,cis-1,3,5-tris(3′,5′-di-tert-butylsalicylaldimino)cyclohexane, spectro-electrochemical and structural studies

A. K. Nairn, R. Bhalla, S. P. Foxon, X. Liu, L. J. Yellowlees, B. C. Gilbert and P. H. Walton, J. Chem. Soc., Dalton Trans., 2002, 1253 DOI: 10.1039/B200571A

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