Issue 7, 2002

A novel two-dimensional copper(ii)–radical complex [Cu(NITmPy)2(N3)2]n: structure and magnetic properties

Abstract

A two-dimensional copper(II)–radical complex [Cu(NITmPy)2(N3)2]n (NITmPy = 2-(3′-pyridyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and characterized by X-ray crystallography. The crystal structure consists of neutral polymeric sheets in which each copper atom is bridged by the oxygen and nitrogen atoms of the NITmPy radical ligands. The variable-temperature magnetic susceptibility data show that the complex exhibits ferromagnetic interactions. The magnetic behavior is discussed in connection with the crystal structure.

Graphical abstract: A novel two-dimensional copper(ii)–radical complex [Cu(NITmPy)2(N3)2]n: structure and magnetic properties

Supplementary files

Article information

Article type
Paper
Submitted
18 Sep 2001
Accepted
25 Jan 2002
First published
08 Mar 2002

J. Chem. Soc., Dalton Trans., 2002, 1350-1353

A novel two-dimensional copper(II)–radical complex [Cu(NITmPy)2(N3)2]n: structure and magnetic properties

L. Li, D. Liao, Z. Jiang and S. Yan, J. Chem. Soc., Dalton Trans., 2002, 1350 DOI: 10.1039/B108476N

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