Issue 22, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

The role of Brønsted acid catalysis in inter-metal ligand exchange reactions

Ian J. Blackmore,a   Vernon C. Gibson,*a   Andrew J. Graham,a   Matthew Jolly,a   Edward L. Marshalla  and  Brian P. Warda  

* Corresponding authors

a Department of Chemistry, Imperial College, South Kensington, London, UK

Abstract

A Brønsted acid is shown to catalyse the inter-metal exchange of mono-anionic (alkoxide and amide) and dianionic (imido) ligands in four-coordinate molybdenum complexes of the type Mo(NR)2(X)2 (R = alkyl, aryl; X = alkoxide, amide).

Graphical abstract: The role of Brønsted acid catalysis in inter-metal ligand exchange reactions

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Article information

DOI
https://doi.org/10.1039/B107460A
Article type
Communication
Submitted
20 Aug 2001
Accepted
05 Oct 2001
First published
17 Oct 2001

J. Chem. Soc., Dalton Trans., 2001, 3242-3243

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The role of Brønsted acid catalysis in inter-metal ligand exchange reactions

I. J. Blackmore, V. C. Gibson, A. J. Graham, M. Jolly, E. L. Marshall and B. P. Ward, J. Chem. Soc., Dalton Trans., 2001, 3242 DOI: 10.1039/B107460A

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