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Issue 15, 2001
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Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

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Abstract

Irradiation of [TpMe2,ClRh(CO)2] [TpMe2,Cl = hydridotris(4-chloro-3,5-dimethylpyrazolyl)borate] in diisopropylamine yields the C–H activated metallacycle [TpMe2,Cl[upper bond 1 start]RhH{CH2CH(CH3)N[upper bond 1 end]HiPr}] as a single diastereomer.

Graphical abstract: Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

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Supplementary files

Article information


Submitted
18 Jun 2001
Accepted
21 Jun 2001
First published
16 Jul 2001

J. Chem. Soc., Dalton Trans., 2001, 2225-2227
Article type
Communication

Diastereoselective C–H bond activation of diisopropylamine at a hydridotris(pyrazolyl)borato rhodium fragment

E. Teuma, F. Malbosc, V. Pons, C. Serra-Le Berre, J. Jaud, M. Etienne and P. Kalck, J. Chem. Soc., Dalton Trans., 2001, 2225
DOI: 10.1039/B105327M

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