Issue 14, 2001

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Abstract

A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereoisomeric ligand renders very low ee's because it does not form a chelated species.

Graphical abstract: Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Supplementary files

Article information

Article type
Communication
Submitted
13 Jun 2001
Accepted
14 Jun 2001
First published
03 Jul 2001

J. Chem. Soc., Dalton Trans., 2001, 2067-2068

Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa and J. Carles Bayón, J. Chem. Soc., Dalton Trans., 2001, 2067 DOI: 10.1039/B105208J

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