Issue 6, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions

Yan Xu,a   Dun-Ru Zhu,a   Zi-Jian Guo,*a   Yu-Jun Shi,a   Kou-Lin Zhanga  and  Xiao-Zeng You*a  

* Corresponding authors

a Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China

Abstract

Two novel hexadecametal–oxygen cluster compounds, {Ni[(NH2)2(C2H4)2NH]2}3[PMoVI5MoV3VIV8O44]·[(NH2)2(C2H4)2NH]·H2O 1 and {Co[(NH2)2(C2H4)2NH]2}2Na[PMoVI6MoV2VIV8O44]·8H2O 2 are synthesized by a hydrothermal method, and characterized by X-ray crystallography, showing that the anion of 1 has a novel tetra-capping mode, and that the first hexadecametal–oxygen host shell is observed in 2.

Graphical abstract: Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions

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Article information

DOI
https://doi.org/10.1039/B010227J
Article type
Communication
Submitted
21 Dec 2000
Accepted
14 Feb 2001
First published
26 Feb 2001

J. Chem. Soc., Dalton Trans., 2001, 772-773

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Cation-induced assembly of the first mixed molybdenum–vanadium hexadecametal host shell cluster anions

Y. Xu, D. Zhu, Z. Guo, Y. Shi, K. Zhang and X. You, J. Chem. Soc., Dalton Trans., 2001, 772 DOI: 10.1039/B010227J

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