Issue 19, 2000
From the journal:

Journal of the Chemical Society, Dalton Transactions

The structure of the LiOMe·2MeOH crystal solvate. A new structural type for tetrameric alkoxides

Zoya A. Starikova,a   Evgeniya P. Turevskaya,b   Nataliya Ya. Turova*b  and  Alexsandr I. Yanovskya  

* Corresponding authors

a Nesmeyanov Institute of Organoelement Compounds, Russian Academy Sciences, Moscow, Russia

b Chemical Department, Lomonosov Moscow State University, Vorobjovy Gory, Moscow, Russia

Abstract

The solvate LiOMe·2MeOH (1) was isolated from a solution of LiOMe in MeOH, its tetrameric unit [Li4(μ-OR)4(μ-ROH)2(ROH)4]·2ROH may be described as two distorted squares [Li2(μ-OR)(μ-ROH)], linked by bridging alkoxy groups and two hydrogen bonds; 1 easily loses the solvate alcohol yielding polymeric LiOMe.

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Article information

DOI
https://doi.org/10.1039/B005782G
Article type
Communication
Submitted
18 Jul 2000
Accepted
16 Aug 2000
First published
05 Sep 2000

J. Chem. Soc., Dalton Trans., 2000, 3237-3238

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The structure of the LiOMe·2MeOH crystal solvate. A new structural type for tetrameric alkoxides

Z. A. Starikova, E. P. Turevskaya, N. Ya. Turova and A. I. Yanovsky, J. Chem. Soc., Dalton Trans., 2000, 3237 DOI: 10.1039/B005782G

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